Does the license deactivate when the program is uninstalled?
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Yes.
When purchasing through Steam, there is no way to add a license to your personal account (even if it is sent by EMAIL)
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The 'account' you have here with a Steam purchase is somewhat obfuscated (by design). That said, the only way to 'add a license' would be via the DLC on the Steam store page.
The only way is to wait for the limit and only during the next installation will it be possible to cancel the previously installed license on the PC.
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While we can free up seats, we cant make it a common practice to do so and only if there is a problem with the license, one that would not allow you the action we discussed, freeing them up yourself when prompted.
Sean Drohan
Stardock Product Lifecycle Manager