It is possible for a champion to get two or more Path-choices, but it is rare. In one of my games, I had chosen Path of the Mage for Procipinee and later could select Path of the Assassin. This happened twice to me since I joined during Beta 3.
Experience works different between champions and normal units. A champion receives full experience, while a units only receives half. If you have more than one champion in the group, the experience gets divided by the number of champions and the normal units receive half of that. Using your numbers, this would mean:
One champion 10 XP (+bonus XP from Potential, etc)
Two champions 5 XP (+bonus XP from Potential, etc) each
Three champions 3 XP (+bonus XP from Potential, etc) each
One champion and three normal units 10 XP (+bonus XP from Potential, etc) for the champion and 5 XP for each of the units
Two champions and three normal units 5 XP (+bonus XP from Potential, etc) for each of the champions and 3 XP for each of the units
I hope this explains it.