OK, this is pretty easy. I see you are the latest Windows 10. I am assuming you have the latest WB and Skinstudio installed.
Open your skin in SkinStudio and go to Theme Part Details, Command Bars. There you will see in the ListView area the "vertical Line" image. That is the left hand line.
Next, go to Edit Explorer/IE Shell Parts, Edit Additional Parts. The left and right lines, add them.
Next, go to Change Skin Colours and use the dropdown to go the the Show me the skin defined system colours area. In the far right (scroll to get their), you will find the colour settings you need to change now for Windows 10. You can change the explorer, folder bar and explorer text colours there. I am working on a new skin here myself, but haven't been able to see if those work yet, still designing in Windows 7 first. Let me know if this works out for you.